Brookfield CAP1000 Viscometer Manual do Utilizador Página 26

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Brookeld Engineering Labs., Inc. Page 24 Manual No. M02-312A0607
APPENDIX A - Variables in Viscosity Measurements
As with any instrument measurement, there are variables that can affect a Viscometer measure-
ment. These variables may be related to the instrument (Viscometer), or the test uid. Variables
related to the test uid deal with the rheological properties of the uid, while instrument variables
would include the Viscometer design and the spindle geometry system utilized.
Rheological Properties
Fluids have different rheological characteristics that can be described by Viscometer measure-
ments. We can then work with these uids to suit our lab or process conditions.
There are two categories of uids:
Newtonian - These uids have the same viscosity at different Shear Rates (different
RPMs) and are called Newtonian over the Shear Rate range they are
measured.
Non-Newtonian - These uids have different viscosities at different shear rates (different
RPMs). They fall into two groups:
1) Time Independent non-Newtonian
2) Time Dependent non-Newtonian
The time dependency is the time they are held at a given Shear Rate (RPM). They are non-
Newtonian, and when you change the Viscometer spindle speed, you get a different viscosity.
Time Independent
Pseudoplastic - A pseudoplastic material displays a decrease in viscosity with an increase
in shear rate, and is also known as “shear thinning”. If you take Viscom-
eter readings from a low to a high RPM and then back to the low RPM,
and the readings fall upon themselves, the material is time independent
pseudoplastic and shear thinning.
Time Dependent
Thixotropic - A thixotropic material has decreasing viscosity under constant shear
rate. If you set a Viscometer at a constant speed, recording P values
over time, and nd that the P values decrease with time, the material is
thixotropic.
Brookeld publication,
“More Solutions to Sticky Problems” includes a more detailed discus-
sion of rheological properties and non-Newtonian behavior.
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